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1

Total Synthesis of Rapamycin

Matthew L. Maddess, Miles N. Tackett, Hidenori Watanabe, Paul E. Brennan, Christopher D. Spilling, James S. Scott, David P. Osborn, Steven V. Ley

Journal:

Angewandte Chemie

Year:

2007

Language:

english

File:

PDF, 195 KB

english, 2007

2

Transfer hydrogenation: A stereospecific method for the conversion of nitro alkanes into amines

Anthony G.M. Barrett, Christopher D. Spilling

Journal:

Tetrahedron Letters

Year:

1988

Language:

english

File:

PDF, 104 KB

english, 1988

3

Support of academic synthetic chemistry using separation technologies from the pharmaceutical industry

Regalado, Erik L., Kozlowski, Marisa C., Curto, John M., Ritter, Tobias, Campbell, Michael G., Mazzotti, Anthony R., Hamper, Bruce C., Spilling, Christopher D., Mannino, Michael P., Wan, Li, Yu, Jin-Q

Journal:

Organic & Biomolecular Chemistry

Year:

2014

Language:

english

File:

PDF, 1.06 MB

english, 2014

4

The Synthesis of 1-Hydroxy Phosphonates of High Enantiomeric Excess Using Sequential Asymmetric Reactions: Titanium Alkoxide Catalyzed P--C Bond Formation and Kinetic Resolution

Rowe, Bradley J., Spilling, Christopher D.

Journal:

Phosphorus Sulfur and Silicon and the Related Elements

Year:

2002

Language:

english

File:

PDF, 189 KB

english, 2002

5

Total Synthesis of Rapamycin

Matthew L. Maddess, Miles N. Tackett, Hidenori Watanabe, Paul E. Brennan, Christopher D. Spilling, James S. Scott, David P. Osborn, Steven V. Ley

Journal:

Angewandte Chemie International Edition

Year:

2007

Language:

english

File:

PDF, 195 KB

english, 2007

6

ChemInform Abstract: Approaches to the Synthesis of Some Tyrosine-Derived Marine Sponge Metabolites: Synthesis of Verongamine (IV) and Purealidin N (X).

Todd R. Boehlow, J. Jonathan Harburn, Christopher D. Spilling

Journal:

Year:

2001

File:

PDF, 33 KB

2001

7

Stereospecific Pd(0)-Catalyzed Arylation of an Allylic Hydroxy Phosphonate Derivative: Formal Synthesis of (S)-(+)-ar-Turmerone.

Bradley J. Rowe, Christopher D. Spilling

Journal:

Year:

2004

File:

PDF, 130 KB

2004

8

Stereospecific Pd(O)-Catalyzed Malonate Additions to Allylic Hydroxy Phosphonate Derivatives: A Formal Synthesis of (-)-Enterolactone.

Bingli Yan, Christopher D. Spilling

Journal:

Year:

2004

File:

PDF, 148 KB

2004

9

Synthesis of Nonracemic Allylic Hydroxy Phosphonates via Alkene Cross Metathesis.

Anyu He, Bingli Yan, Anchalee Thanavaro, Christopher D. Spilling, Nigam P. Rath

Journal:

Year:

2005

File:

PDF, 51 KB

2005

10

Allylic Hydroxy Phosphonates: Versatile Chiral Building Blocks.

Antonette De la Cruz, Anyu He, Anchalee Thanavaro, Bingli Yan, Christopher D. Spilling, Nigam P. Rath

Journal:

Year:

2005

File:

PDF, 35 KB

2005

11

ChemInform Abstract: Stereoselective Synthesis of Cyclic Ethers via the Palladium-Catalyzed Intramolecular Addition of Alcohols to Phosphono Allylic Carbonates.

Anyu He, Nongnuch Sutivisedsak, Christopher D. Spilling

Journal:

Year:

2010

Language:

english

File:

PDF, 42 KB

english, 2010

12

Determination of the enantiomeric purity and absolute configuration of α-hydroxy phosphonates

James K. Kozlowski, Nigam P. Rath, Christopher D. Spilling

Journal:

Year:

1995

Language:

english

File:

PDF, 855 KB

english, 1995

13

The preparation and reactions of chiral phosphorous acid diamides

Kevin J. Koeller, Christopher D. Spilling

Journal:

Tetrahedron Letters

Year:

1991

Language:

english

File:

PDF, 290 KB

english, 1991

14

The regio- and stereo- selective epoxidation of alkenes with methyl trioxorhenium and urea-hydrogen peroxide adduct

Todd R. Boehlow, Christopher D. Spilling

Journal:

Tetrahedron Letters

Year:

1996

Language:

english

File:

PDF, 215 KB

english, 1996

15

Synthesis and kinetic analysis of some phosphonate analogs of cyclophostin as inhibitors of human acetylcholinesterase

Supratik Dutta, Raj K. Malla, Saibal Bandyopadhyay, Christopher D. Spilling, Cynthia M. Dupureur

Journal:

Bioorganic & Medicinal Chemistry

Year:

2010

Language:

english

File:

PDF, 682 KB

english, 2010

16

Concise synthesis of 1,3-di-O-substituted tetrahydropyran derivatives as conformationally stable pyranose mimetics

Laurel K. Mydock, Christopher D. Spilling, Alexei V. Demchenko

Journal:

Comptes Rendus Chimie

Year:

2011

Language:

english

File:

PDF, 244 KB

english, 2011

17

Allylic hydroxy phosphonates: versatile chiral building blocks

Antonette De la Cruz, Anyu He, Anchalee Thanavaro, Bingli Yan, Christopher D. Spilling, Nigam P. Rath

Journal:

Journal of Organometallic Chemistry

Year:

2005

Language:

english

File:

PDF, 316 KB

english, 2005

18

Chemistry of glucal halohydrins(II): An unusual protecting group effect in the competitive formation of formyl furanosides and methyl glycosides

John S. Kozlowski, Cecilia H. Marzabadi, Nigam P. Rath, Christopher D. Spilling

Journal:

Carbohydrate Research

Year:

1997

Language:

english

File:

PDF, 1.11 MB

english, 1997

19

The chemistry of glucal halohydrins: The effect of the halide on epoxide formation

Cecilia H. Marzabadi, Christopher D. Spilling, Lisa M. Tyler

Journal:

Year:

1994

Language:

english

File:

PDF, 1013 KB

english, 1994

20

Facile intramolecular ene reactions of steroidal unsaturated acyloins

Brian A. Marples, Christopher D. Spilling

Journal:

Year:

1992

Language:

english

File:

PDF, 730 KB

english, 1992

21

The intramolecular ene reaction of 5-(prop-2-enyl)-2ξ-hydroxy- 5α-cholestan-3-one.

Brian A. Marples, Christopher D. Spilling

Journal:

Year:

1994

Language:

english

File:

PDF, 581 KB

english, 1994

22

The synthesis, structure and properties of diazaphospholes: Reagents and ligands for asymmetric synthesis

Antonette De la Cruz, Kevin J Koeller, Nigam P Rath, Christopher D Spilling, Isabel C.F Vasconcelos

Journal:

Year:

1998

Language:

english

File:

PDF, 783 KB

english, 1998

23

The enantioselective addition of dialkylphosphites to aldehydes: Catalysis by a lanthanum binaphthoxide complex

Nigam P. Rath, Christopher D. Spilling

Journal:

Tetrahedron Letters

Year:

1994

Language:

english

File:

PDF, 354 KB

english, 1994

24

The ene reaction of 5-allyl-2ϵ-hydroxy-5α-cholestan-3-one: An unusually facile ene reaction

Brian A. Marples, Christopher D. Spilling

Journal:

Tetrahedron Letters

Year:

1987

Language:

english

File:

PDF, 219 KB

english, 1987

25

Ene reactions of unsaturated acyloins

Brian A Marples, Christopher D Spilling

Journal:

Tetrahedron Letters

Year:

1985

Language:

english

File:

PDF, 211 KB

english, 1985

26

Stereocontrolled total synthesis of the penicillanate ester (2S,5R)-benzyl 3,3-dimethyl-7-oxo-4-thia-1-azabicyclo [3.2.0] heptane-2-carboxylate

Anthony G.M Barrett, Minn-Chang Cheng, Santi Sakdarat, Christopher D Spilling, Sven J Taylor

Journal:

Tetrahedron Letters

Year:

1989

Language:

english

File:

PDF, 140 KB

english, 1989

27

Substituent effects in the reaction of allyl trichloroacetimidates with N-halosuccinimides: Cyclization vs aza-Claisen rearrangement

Hossein Shabany, Christopher D. Spilling

Journal:

Tetrahedron Letters

Year:

1998

Language:

english

File:

PDF, 239 KB

english, 1998

28

New homochiral cyclic diol ligands for titanium alkoxide catalyzed phosphonylation of aldehydes

Michael D. Groaning, Bradley J. Rowe, Christopher D. Spilling

Journal:

Tetrahedron Letters

Year:

1998

Language:

english

File:

PDF, 231 KB

english, 1998

29

The synthesis of 1-hydroxy phosphonates of high enantiomeric excess using sequential asymmetric reactions: titanium alkoxide-catalyzed PC bond formation and kinetic resolution

Bradley J. Rowe, Christopher D. Spilling

Journal:

Tetrahedron: Asymmetry

Year:

2001

Language:

english

File:

PDF, 180 KB

english, 2001

30

Preparation and structure of new homochiral diazaphosphole ligands and their platinum(II) chloride complexes

Isabel C.F Vasconcelos, Gordon K Anderson, Nigam P Rath, Christopher D Spilling

Journal:

Tetrahedron: Asymmetry

Year:

1998

Language:

english

File:

PDF, 179 KB

english, 1998

31

New homochiral amino-phosphine ligands: application in asymmetric palladium catalyzed allylic alkylation

Isabel C.F Vasconcelos, Nigam P Rath, Christopher D Spilling

Journal:

Tetrahedron: Asymmetry

Year:

1998

Language:

english

File:

PDF, 140 KB

english, 1998

32

Asymmetric synthesis of α-hydroxy- phosphonamides, phosphonates and phosphonic acids

Vincent J. Blazis, Kevin J. Koeller, Christopher D. Spilling

Journal:

Tetrahedron: Asymmetry

Year:

1994

Language:

english

File:

PDF, 318 KB

english, 1994

33

Release of iron from transferrin by phosphonocarboxylate and diphosphonate chelating agents

Wesley R. Harris, Claire E. Brook, Christopher D. Spilling, Sampathkumar Elleppan, Wang Peng, Meiguo Xin, Jennifer Van Wyk

Journal:

Journal of Inorganic Biochemistry

Year:

2004

Language:

english

File:

PDF, 620 KB

english, 2004

34

An intramolecular NH⋯Co hydrogen bond and a structure correlation study of the pathway for protonation of the Co(CO)3L− anion (L=CO, PR3)

Lee Brammer, Juan C. Mareque Rivas, Christopher D. Spilling

Journal:

Journal of Organometallic Chemistry

Year:

2000

Language:

english

File:

PDF, 161 KB

english, 2000

35

The preparation of acyl phosphonates by the heterogeneous oxidation of 1-hydroxy phosphonates

Yihua Liao, Hossein Shabany, Christopher D. Spilling

Journal:

Tetrahedron Letters

Year:

1998

Language:

english

File:

PDF, 266 KB

english, 1998

36

Efficient Synthesis of Tyrosine-Derived Marine Sponge Metabolites via Acylation of Amines with a Coumarin

Harburn, J. Jonathan, Rath, Nigam P., Spilling, Christopher D.

Journal:

Journal of Organic Chemistry

Year:

2005

Language:

english

File:

PDF, 199 KB

english, 2005

37

Asymmetric Synthesis of 2-Alkyl-3-phosphonopropanoic Acids via P−C Bond Formation and Hydrogenation

Badkar, Pallavi A., Rath, Nigam P., Spilling, Christopher D.

Journal:

Organic Letters

Year:

2007

Language:

english

File:

PDF, 195 KB

english, 2007

38

Stereoselective Synthesis of Cyclic Ethers via the Palladium-Catalyzed Intramolecular Addition of Alcohols to Phosphono Allylic Carbonates

He, Anyu, Sutivisedsak, Nongnuch, Spilling, Christopher D.

Journal:

Organic Letters

Year:

2009

Language:

english

File:

PDF, 323 KB

english, 2009

39

REACTIONS OF CHIRAL PHOSPHORUS ACID DIAMIDES: LEWIS ACID CATALYZED ADDITION TO IMINES AND OXIDATION WITH SnCl4

Koeller, Kevin J., Rath, Nigam P., Spilling, Christopher D.

Journal:

Phosphorus Sulfur and Silicon and the Related Elements

Year:

1995

Language:

english

File:

PDF, 674 KB

english, 1995

40

Synthesis and Biological Evaluation of Purpurealidin E-Derived Marine Sponge Metabolites: Aplysamine-2, Aplyzanzine A, and Suberedamines A and B

Kottakota, Suresh K., Evangelopoulos, Dimitrios, Alnimr, Amani, Bhakta, Sanjib, McHugh, Timothy D., Gray, Mark, Groundwater, Paul W., Marrs, Emma C. L., Perry, John D., Spilling, Christopher D., Harbu

Journal:

Journal of Natural Products

Year:

2012

Language:

english

File:

PDF, 2.42 MB

english, 2012

41

Poster 23: Oncologists' and Physiatrists' Attitudes Regarding Rehabilitation for Patients With Advanced Cancer

Gayle R. Spill, Christopher Daugherty, Fay J. Hlubocky, Mark Siegler

Journal:

Archives of Physical Medicine and Rehabilitation

Year:

2008

Language:

english

File:

PDF, 44 KB

english, 2008

42

Effects of proline analog binding on the spectroscopic and redox properties of PutA

Weidong Zhu, Yekaterina Gincherman, Paul Docherty, Christopher D Spilling, Donald F Becker

Journal:

Archives of Biochemistry and Biophysics

Year:

2002

Language:

english

File:

PDF, 190 KB

english, 2002

43

Synthesis and Kinetic Evaluation of Cyclophostin and Cyclipostins Phosphonate Analogs As Selective and Potent Inhibitors of Microbial Lipases

Point, Vanessa, Malla, Raj K., Diomande, Sadia, Martin, Benjamin P., Delorme, Vincent, Carriere, Frederic, Canaan, Stephane, Rath, Nigam P., Spilling, Christopher D., Cavalier, Jean−François

Journal:

Journal of Medicinal Chemistry

Year:

2012

Language:

english

File:

PDF, 604 KB

english, 2012

44

Stereoselective Reactions of Allylic Hydroxy Phosphonates

De La Cruz, M. Antonette, Shabany, Hossein, Spilling, Christopher D.

Journal:

Phosphorus Sulfur and Silicon and the Related Elements

Year:

1999

Language:

english

File:

PDF, 190 KB

english, 1999

45

Oncologists' and Physiatrists' Attitudes Regarding Rehabilitation for Patients With Advanced Cancer

Gayle R. Spill, Fay J. Hlubocky, Christopher K. Daugherty

Journal:

Year:

2012

Language:

english

File:

PDF, 2.45 MB

english, 2012

46

PENILE PROSTHESIS INSERTION IN PEYRONIE'S DISEASE

G. Garaffa, A. Sacca, A.M. Abdel Raheem, D. Deho, A. Salonia, A. Spillings, S. Minhas, A.N. Christopher, F. Montorsi, D.J. Ralph

Journal:

European Urology Supplements

Year:

2008

Language:

english

File:

PDF, 67 KB

english, 2008

47

TOTAL PHALLIC CONSTRUCTION USING THE FOREARM FREE FLAP

G. Garaffa, A.M. Abdel Raheem, A. Spillings, A.N. Christopher, D.J. Ralph

Journal:

European Urology Supplements

Year:

2008

Language:

english

File:

PDF, 67 KB

english, 2008

48

Stereospecific Pd(0)-Catalyzed Arylation of an Allylic Hydroxy Phosphonate Derivative: Formal Synthesis of ( S )-(+)-ar-Turmerone

Rowe, Bradley J., Spilling, Christopher D.

Journal:

Journal of Organic Chemistry

Year:

2003

Language:

english

File:

PDF, 210 KB

english, 2003

49

Effect of Ligand Structure on the Pathways for Iron Release from Human Serum Transferrin

Brook, Claire E., Harris, Wesley R., Spilling, Christopher D., Peng, Wang, Harburn, J. Jonathan, Srisung, Sujittra

Journal:

Inorganic Chemistry

Year:

2005

Language:

english

File:

PDF, 100 KB

english, 2005

50

Enantioselective Inhibition of Microbial Lipolytic Enzymes by Nonracemic Monocyclic Enolphosphonate Analogues of Cyclophostin

Point, Vanessa, Malla, Raj K., Carrière, Frederic, Canaan, Stéphane, Spilling, Christopher D., Cavalier, Jean-François

Journal:

Journal of Medicinal Chemistry

Year:

2013

Language:

english

File:

PDF, 492 KB

english, 2013

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